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Figure 5: a) (left) Chemical resistance; and b) (right) Thermal resistance of SELFA.
                                                                              using pre-UV. The resin in the adhesive
                                                                              is chemically bonded and makes a
                                                                              three-dimensional network by use of the
                                                                              405nm UV irradiation. This chemical
                                                                              networking improves the stability of the
                                                                              adhesive and prevents delamination.
                                                                                Thermal resistance was evaluated by
                                                                              observing the delamination behavior
                                                                              of the wafer/SELFA/glass structure
                                                                              during and after heating.  Figure
                                                                              5b  shows the evaluation scheme
                                                                              of the thermal resistance and the
                                                                              appearance of the wafer/SELFA/glass
                                                                              structure after evaluation. Thermal
                                                                              resistance was evaluated after pre-UV
                                                                              irradiation. Two thermal conditions
                                                                              were prepared as follows: 1) hot plate,
                                                                              and 2) reflow, which were set up as
                                                                              simulations of thermal processes,
                                                                              such as redistribution layer (RDL)
                                                                              curing and soldering, respectively.
                                                                              Delamination was not observed after
                                                                              3 cycles at 220°C x 2hr treatment on
                                                                              the hot plate in atmosphere.  Likewise,
                                                                              delimitation was not observed after 10
                                                                              cycles at 260°C x 5min treatment in
                                                                              the reflow process. Delamination was
        Figure 6: a) (top) Appearance of a 20µm-thick wafer; and b) (bottom) Several types of wafers after glass debonding.  prevented  because  outgassing  from
        an additional planarization process.   tape against solvents and conditions   SELFA was decreased by using thermal
        This TTV value is the same as for the   used in wet processing. The weight   resistant material for the acrylic resin,
        other temporary bonding materials [9].   loss values of SELFA were <2% in any   base film, low polarity component, and
        No edge crack was observed from the   of the conditions we evaluated. This   the gas generator, which are stable in
        wafer edge.                        means that the new tape is stable in   high temperature, such as <260°C. The
          Chemical resistance was evaluated   these solvents and can safely support   combination test of hot plate and reflow
        by measuring the weight loss of SELFA   wafers in wet processes. This chemical   was also evaluated. Delamination
        in several solvents. Figure 5a shows   resistance  is enabled by chemical   was not observed after continuous
        the chemical resistance of the new   crosslinking of the adhesion layer by   treatment of 220°C x 2hr on a hot plate

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