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Increasing passivation and reducing the   Acknowledgements                 M. Gruffat, N. Launay, N. Arnal,
        fluorine-free radical concentration helps   This work was supported by the Science   P. Godinat, “Fabrication of 3D
        in the reduction of ER of the oxide at the   and Engineering Research Council of   packaging TSV using DRIE,” 2008
        top corner. However, because of lower   A*STAR (Agency for Science, Technology   Symp. on Design, Test, Integration
        passivation at the bottom of the TSV, the   and Research), Singapore, under Grant No.   and Packaging of MEMS/MOEMS,
        oxide is continuously sputtered to the   12101E0008. Portions of this article were   Nice, France, 2008, pp. 109-114, doi:
        sidewalls and results in a higher ER.  originally presented at the 2022 IEEE   10.1109/DTIP.2008.4752963.
          To understand the optimized process   24th Electronics Packaging Technology   8. V.  M.  Don nelly,  “Reactions
        window for the DOE, JMP software is   Conference (EPTC) and has been edited   of fluorine atoms with silicon,
        used to generate the predictive profile   for publication in Chip Scale Review.  revisited, again,” Jour. of Vacuum
        as shown in Figure 5a. The dependent                                       Science  &  Tech.  A:  Vacuum,
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                       Biographies
                         Bhesetti S. S. Chandra Rao is a Senior Scientist at the Institute of Microelectronics, Agency for Science,
                       Technology and Research (A*STAR), Singapore. His research interests are 3D-IC, C2W and W2W bonding and
                       dry etch process technologies. He received a PhD from the NUS Singapore, a Master’s degree from the IISc,
                       Bangalore, and a Bachelors degree from the NIT, Warangal, India. Prior to this, he worked for 9 years at Lam
                       Research and Applied Materials in dry etch technology. He has served EPTC2021 as a Technical Chair and
                       General Chair for IEEE-EPTC 2022. Email Bhesetti_Chandra_Rao@ime.a-star.edu.sg

            Hemanth Kumar Cheemalamarri is a Scientist at the Institute of Microelectronics, Agency for Science, Technology and
          Research (A*STAR), Singapore. He completed his PhD from IIT Hyderabad, India, 2021. He is currently working as a research
          scientist in W2W bonding technology for heterogeneous integration and MEMS applications.


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