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to reach an equilibrium state with the   containment is to prevent liquid overflow   Therefore, if the boundary is created by
        lowest surface energy. This mechanism   outside the bonding area, which would   lithographic means, the final alignment
        results in self alignment of the die with   cause misalignment. Containment can   will depend on the capabilities of the
        its bonding site. Water was chosen as   be achieved through physical means   lithographic process
        the working medium because of its high   and/or chemical surface contrast.   After  self  alignment,  the  water
        surface tension, which produces strong   Physical contrast is achieved by creating   evaporates and direct bonding occurs
        capillary forces that can be harnessed   a border around the bonding site,   due to the spontaneous adhesion of
        to drive self alignment. Moreover,   whereas chemical contrast is obtained   the specially-prepared die and wafer
        water is environmentally friendly and   by depositing a hydrophobic material   su r faces, w it hout requ i r i ng a ny
        its evaporation is easily controlled in a   around the periphery of the hydrophilic   intermediate layer. For good bonding
        monitored environment. Finally, water   bonding area. Water containment is   quality, both the die and wafer must
        has the additional advantage of being   maximized by combining both chemical   meet strict bow, nanotopography and
        compatible with direct bonding and is   and physical contrasts, resulting in the   surface roughness requirements. Any
        already used in hydrophilic bonding   best possible self-alignment outcome   organic or particulate contamination
        mechanisms.                        (Figures 2 and  3). The extent of   of the bonding surfaces may impede
          To ensure self alignment, good   alignment is linked to the accuracy of   bonding. Those parameters, therefore,
        containment of water on the bonding site   the step and by the definition of the   must be critically controlled to ensure
        is critical (Figure 1). The aim of this   hydrophilic/hydrophobic boundary.   good quality bonding.

                                                                              Collective vs. direct-placement
                                                                              P&P
                                                                                To d ay, d i r e c t- pla c e me nt D2W
                                                                              relies on robotics and optics for the
                                                                              die handling, alignment and bonding
                                                                              steps. A major advantage of our self-
                                                                              assembly process is that it avoids the
                                                                              need for mechanical movements during
                                                                              the alignment and bonding steps by
                                                                              exploiting the physical phenomenon
                                                                              of surface  tension, provided by the
                                                                              water droplet, to induce self alignment
        Figure 2: Water contact angle of hydrophilic bonding site and hydrophobic surrounding area.  and bonding with the wafer (Table 1).
                                                                              Precise alignment is, therefore, achieved
                                                                              at a high-throughput rate. The handling
                                                                              step can, therefore, be faster because
                                                                              it requires lower accuracy (<200µm)
                                                                              compared to direct-placement P&P.
                                                                              Consequently, the estimated throughput
                                                                              for the overall process should reach
                                                                              more than 2,000 dies per hour.
                                                                                Another possibility consists in using
                                                                              the direct-placement D2W process for
                                                                              collective assembly (Figure 4). All
                                                                              dies, therefore, can be positioned on
                                                                              a holder or a tape with low placement
                                                                              accuracy and at high speed. Then, the
                                                                              dies can be prepared as a group and
                                                                              placed roughly opposite their bonding
                                                                              sites. A technique is then necessary to
                                                                              release the dies onto the water droplets.
                                                                              The water droplet completes the fine
                                                                              alignment of the dies to less than 400nm
        Figure 3: Hydrophilic bonding pad surrounded by hydrophobic area for water containment.  3σ. This collective approach to assembly
                                                                              could drastically increase throughput.

                                                                              A short history of self-assembly
                                                                              development
                                                                                Self-assembly processes have been
                                                                              investigated by many groups in centers
                                                                              all over the world, such as: Tohoku
        Table 1: Impact of self-assembly on the die to wafer process.

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